Published

Transition from a Simple Auxiliary Anode to a Fully-developed Conforming Anode System for Plating

This paper demonstrates that the use of an elaborate CAE designed conforming anode system enables plating complex exterior automotive part designs within specification.  It will be shown that the increased fixed and variable production costs that are unavoidable when operating an elaborate conforming anode system can be partially earned back by a reduction in metal consumption, and by an increased capacity due to shorter plating times.
#research #surfin #automotive

Share

The presentation is a two-part discussion of the use of computer-aided engineering in designing a conforming anode for chromium plating of parts with complex geometries.

Introduction and design challenges presented by LaRon Brown, Ford Motor Company

The aesthetics of automotive design can challenge the capability of plating manufacturing.  The design of a part is critical to the overall manufacturing feasibility and part performance.  Both design and engineering must determine if a particular design can be plated to specification.  Prior to the advent of computer-aided engineering (CAE) software, suppliers identified design challenges based on experience more than anything else.  Prototype tooling and plating racks were developed after the molding die was cut.  Thus, it was only after a part was molded that a design concern was discovered, such as low plate thickness or other shortcomings. 

Featured Content

Figure 1 - Examples of design problems addressed by CAE software.

Elsyca NV, in Leuven, Belgium, has pioneered the development of CAE software in electrochemical process modeling.  Their work extends to surface finishing and electrochemical manufacturing, as well as corrosion design engineering, cathodic protection and AC mitigation.***  This technology provides accurate verification of design constraints through computer simulation rather than subjective experience.

CAE software offers plating simulation technology which enables upfront consideration of design related manufacturing issues, as shown in Fig. 1.  The software can be used to support supplier process quality and improve warranty.  In Fig 1(a), an area (arrow) is found to have under-spec chromium thickness, which can be corrected by redesign, etc., to ensure in-field service with no corrosion.  Figure 1(b) shows CAE software used for rack optimization.  Further, cost savings can be gained in the design process by identifying areas of excessive plate thickness, as in Fig. 1(c).

Figure 2 shows another example where part design of a B-side flange takes the plating process into account, long before the first part is manufactured.  At the left, the design concept involves a flange with a 300-mm depth, and CAE analysis shows that the nickel thickness would be below the spec of 21 μm over 90% of the part area.  On the right, redesign to a shallower 88-mm depth is shown to meet the nickel thickness specification, with minimal plate thickness coverage increasing over 75% of the part.

Figure 2 - Plate thickness analysis of a B-side flange in the design stage, showing the effect of flange depth on nickel thickness.

An example of rack optimization is shown in Fig. 3.  Here, six grilles are arranged on the rack, with the outer surfaces facing out in a convex pattern, as seen in the top view (left).  The anodes are arranged in a curved line opposite the rack.  The table (right) shows the computer-calculated thickness for positions 1 and 2 on the rack, at the P-points, i.e., those critical quality points where the thickness spec must be met.  The red areas in the table indicate where the specs are not met by the anode configuration.  Adjusting the geometry can be done onscreen to correct these potential shortcomings.

Figure 3 - Analysis of plate distribution on individual grilles for optimization between the rack and the anode configuration in the plating tanks.

Using Conforming Anodes to Improve Plate Thickness presented by Bart Van den Bossche, Elsyca NV

What follows is a case study of the use of conforming auxiliary anodes in the Cu-Ni-Cr of a truck grille.  The grille is similar to those illustrated previously in Fig. 3.  The front of the grille is a Class A surface, i.e., one that is visible in the product and thus must be of high efficiency and quality.  The back of the grille is a Class C surface, i.e., one that is not visible and can have tool marks and other surface disparities that are not a factor in product appearance.  However, plated metal is deposited on the grille backside, albeit a smaller amount, because the anodes are placed opposite the front surface.

A study was first made of a grille produced via the “default” plating process, i.e., with no auxiliary anodes, and the main tank anodes fed by the main rectifier.  The production cycle is as follows (Table 1), where J is the average current density, E is the excess plating factor to account for the deposit on the Class C backside surface and I is the total imposed current:

Table 1 - Default plating process conditions

Figure 4 - Total nickel thickness distribution under default processing conditions.

Under these conditions, the CAE software developed the nickel thickness distribution is shown in Fig. 4, where 87.9% of the Type A surface was found to be above specification.  Corresponding figures for copper and chromium were 86.3 and 97.3%, respectively.  The nickel deposit was below specification in the fillet areas circled in the figure and shown in the enlargements.  Also, the buildup on the outer corners was quite high, raising concern over nodular nickel growth in these areas.

Figure 5 - CAE optimized anode and shield system.

A conforming auxiliary anode system was then developed and optimized.  The result, shown in Fig. 5, uses insulating shields to protect the corners and reduce the risk of nodule nickel growth.  A selectively activated titanium rod structure was used to increase current to the areas otherwise subject to low current density.  The operating conditions are outlined in Table 2, where Imain and Iaux are the total imposed currents delivered, respectively, by the main rectifier through the main tank anodes, and the auxiliary rectifier through the conforming anode system.

Table 2 - Process conditions for the CAE optimized conforming anode system.

 

Figure 6 - Total nickel thickness distribution with the CAE optimized conforming anode system.

 

 

With the CAE optimized anode system, the computer-determined nickel thickness distribution is shown in Fig. 4, where 87.9% of the Type A surface remained above specification.  The nickel deposit was considerably improved in the fillet areas circled in the figure and shown in the enlargements.  Also, the risk of nodular buildup on the outer corners was considerably reduced.  The CAE designed conforming anode system drastically enhanced the throwing power.

Some fillet areas (11%) were found to be above half-thickness specifications and hence would probably pass salt spray tests.  A few fillets (<1%) still remained below half-thickness specifications, but could be mitigated by part redesign, e.g., increasing the fillet radius. 

In terms of economics, additional handling of the front side conforming anode system would cause a significant increase of the variable cost.  The rack hardware (fixed cost) would also become several times higher than the cost for racks without auxiliary anodes.

The copper and nickel material costs savings are hard to calculate because the default case does not meet specifications for about 25% of the Class A surface.  As a rough estimate, it can be stated that the plating time of the nickels in the default case would need to be 50% longer, and hence 120 g of additional nickel is deposited, corresponding to a cost of about US $1 to 2 per part.

In summary, the examples presented here show the value of the CAE software of today to automotive design.  The case of its use in automotive decorative plating is clear.  With the ability to calculate plate distribution before tooling and prototype parts are even produced, design is immeasurably enhanced.

About the authors / presenters

LaRon Brown is Decorative Finishes Technology Specialist at Ford Motor Company, Dearborn, Michigan.  She has a Six Sigma Black Belt Certification, SMI in paint and chromium plating processing, material development, plastics injection molded technologies and corrosion protection.  She has diverse professional experience in the automotive industry and in injection molding processes in particular.  She also has technical support responsibility for exterior chromium parts, development and CAE tools associated with the implementation of exterior decorative finishes.

Dr. Bart Van den Bossche graduated from the Vrije Universiteit Brussel (VUB, Belgium) with a M.Sc. degree in Metallurgical Engineering in 1991.  He received a Ph.D. in Electrochemical Engineering in 1998.  Bart is Elsyca’s Engineering Manager for Surface Finishing projects.  Bart has been active in electrochemical process computer modeling for nearly 25 years, as reflected in a series of peer reviewed papers.  In addition, he has a long track record as a consultant for electrochemical cell and tooling design in the plating, electroforming and electrochemical machining industry.  As Elsyca co-founder, Bart is in charge of several Elsyca consulting projects.

 

*Compiled by Dr. James H. Lindsay, NASF Technical Editor

** Corresponding authors:

LaRon M. Brown, Technical Specialist

Decorative Finishes Application and Development

Body Exteriors - Core

Ford PDC 2B-C71

Ford Motor Company

20901 Oakwood Blvd.

Dearborn, MI 48124

Phone:  313-594-1509

Fax:      313-621-4541

E-mail:  lbrow102@ford.com

Dr. Bart Van den Bossche

Elsyca NV

Vaartdijk 3, Bus 603

B3018 Wijgmaal

Belgium

Phone:  +32 16 47 49 60

E-mail: bart.van-den-bossche@elsyca.com

 

*** B. Van den Bossche, et al., Plating & Surface Finishing, 95 (5), 35-38 (2009); 95 (10), 46-54 (2009); 95 (12), 24-35 (2009); 96 (9), 58-64 (2010) (these and earlier references available online at NASF/NCMS Surface Technology Resource Center Library: www.sterc.org).

A Class B surface is one that is visible but where appearance is less important, such as interior surfaces in glove boxes, etc.

RELATED CONTENT

  • Cyanide Destruction: A New Look at an Age-Old Problem

    Cyanide in mining and industrial wastewaters has been around from the beginning, including electroplating processes.  This presentation reviews a number of current processes, and in particular, offers new technologies for improvement in cyanide destruction by the most common process, using sodium hypochlorite.

  • Hybrid Sol-Gel Coatings in Surface Engineering

    A look at the use of modified sol-gel polymer films and hybrid system coatings, as well as the methodologies for evaluating the mechanical properties of the coatings.

  • Defects in Hard Chromium Deposits Part I: Causes and Cures

    The causes of and remedies for defects in hard chromium deposits are explored in the first of this two-part P&SF article from 1984.  Photomicrographs and SEM (scanning electron microscope) photo­graphs will illustrate that most defects in various hard chromium deposits arise from defects in the basis metal. These defects may be in the original metal surface or may be caused by preplate finishing. Homogeneous hard chromium deposits can be produced only by eliminating these defects. Practical suggestions and procedures will be given.