Wide Cure Windows
Why do epoxy electrocoat materials have more flexibility in curing conditions?
Q. Why do epoxy electrocoat materials have a wide cure window in terms of temperature and time? What allows this flexibility? —J.M.
A. The typical automotive epoxy electrocoat primer coating consists of an amino-epoxy resin formulated in combination with a blocked di-isocyanate crosslinker that, when baked at temperatutes greater than 170°C, polymerizes and crosslinks to form epoxy-urethane-chained structures. These estructures provide excellent mechanical, chemical and corrosion properties in a variety of combinations of film crosslinking densities and/or molecular weights.
Because the degree of epoxy-urethane crosslinking and molecular weight is directly proportional to the time and temperature of exposure of the electrocoat film during oven cure, the e-coat paint can provide good to excellent performance at multiple degrees of crosslinking. In other words, it provides a wide window of operation and provides excellent resistance under multiple overbaking or underbaking conditions.
The mechanical, physical and chemical properties of the cured film are specific to each crosslinking density’s time/temperature values during curing. Some properties improve with increased crosslinking densities and others don’t.
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This paper is a peer-reviewed and edited version of a presentation delivered at NASF SUR/FIN 2012 in Las Vegas, Nev., on June 12, 2012.
E-coat can produce uniform finishes with excellent coverage and outstanding corrosion resistance.